{4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methylidene]benzohydrazidato-κ2 N′,O}dimethyltin(IV)
نویسندگان
چکیده
In the title complex, [Sn(CH3)2(C18H11ClN2O2)], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal-bipyramidal geometry [Sn-O = 2.092 (3) and 2.144 (3) Å; Sn-N = 2.160 (4) Å]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6 (2)°. In the crystal, adjacent mol-ecules are linked by weak C-H⋯O hydrogen bonds, forming a chain along the b-axis direction.
منابع مشابه
{4-Amino-N′-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidato}dimethyltin(IV)
In the title compound, [Sn(CH3)2(C18H13N3O2)], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 4-amino-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate(2-) ligand and two C atoms from methyl ligands in a distorted trigonal-bipyramidal geometry. The dihedral angle between the naphthalene ring system and the benzene ring is 19.2 (2)°. In the crystal, weak N-H⋯O...
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متن کاملDibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2 N′,O 2}tin(IV)
The five-coordinate Sn(IV) atoms in the two crystallographically independent mol-ecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N'-[1-(5-chloro-2-oxidophen-yl)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazide, displays inter-molecular O-H⋯N hydrogen bondi...
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013